A Versatile Route To Cyclic (Alkyl)(Amino)Carbene?Stabilized Stibinidenes

نویسندگان

چکیده

A convenient route for the synthesis of cAACMe (cAAC=cyclic (alkyl)(amino)carbene, cAACMe=1-(2,6-di-iso-propylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene) and cAACCy (cAACCy=2-azaspiro[4.5]dec-2-(2,6-diisopropylphenyl)-3,3-dimethyl-1-ylidene) stabilized stibinidenes cAACMe?SbMes (2 a) (Mes=2,4,6-trimethylphenyl) cAACCy?SbMes b) is reported. mechanism formation [cAACRCl][SbCl3Mes] 1 cAACR?SbMes 2 from reaction cAAC with antimony(III) precursor SbCl2Mes, which proceeds via isolable intermediate [cAACRSbClMes][SbCl3Mes] (3), proposed.

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ژورنال

عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie

سال: 2022

ISSN: ['0044-2313', '1521-3749']

DOI: https://doi.org/10.1002/zaac.202200085